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- W2185293670 abstract "Materialsconfinedattheatomicscaleexhibit� unusualpropertiesduetonanoconfinementeffect.� Chemistryinaconfinednanospacemaythus� bedifferentfromthatofbulksystem. � W ehave� demonstratedforthefirsttimetheintrinsicrole� ofnanoconfinementinfacilitatingthechemical� reductionofmetalionprecursorswithasuitable� reductantforthesynthesisofmetalnanoparticles,� whentheidenticalreactiondoesnotoccurinbulk� solution.� T akingthecaseofcitratereductionof� silverionsundertheunusualconditionof �(citrate)/ (Ag+)� » � 1, � ithasbeenobservedthatthesilver� citratecomplex, �stableinbulksolution, �decomposes� readilyinconfinednanodomainsofchargedand� neutralmatrices � (ion-exchangefilmandporous� polystyrenebeads), �leadingtotheformationofsilver� nanoparticles.1�Ithasbeenexperimentallyobserved� thatthenanoconfinedredoxdecompositionofsilver� citratecomplexisresponsiblefortheformationofAg� seeds,�whichthereaftercatalyzeoxidationofcitrate� andactaselectronsinkforsubsequentreduction� ofsilverions. �Atpresent, �thereisnoschemeforin� situformationofAgnanoparticlesusingAg+ �ions� inanion-exchangeandneutralmatrices. � TheAg� nanoparticlesthusformedareuncapped, � stable� andeasilyaccessiblethroughinterconnectedpores� orchannelsinthematrices. � Theeasyretrieval� ofthematrixsupportednanoparticlesfromthe� systemsmakesthemreusablenanocatalystswithout� contaminatingtheproductsandsystem." @default.
- W2185293670 created "2016-06-24" @default.
- W2185293670 creator A5038472163 @default.
- W2185293670 date "2014-01-01" @default.
- W2185293670 modified "2023-09-27" @default.
- W2185293670 title "Redox Reactions in Nanoscale Confinement" @default.
- W2185293670 hasPublicationYear "2014" @default.
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