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- W2185486581 abstract "In this work an experimental study based on the structure, stability and formation rate of the complex formed between Al(III) and 2´(OH)acetophenone in methanol and ethanol using UV-visible spectroscopy was carried out. The influences of the temperature (15-35°C), ionic strength (1,7x10 -3 -7,8x10 -3 M) and the relative permittivity of the solvent (e r = 24,55 and 32,63) on the reaction rate were studied. A complex of 1:1 stoichiometry was obtained by means of the molar ratio method. The formation complex constant was calculated in methanol (KC= 6,08x10 5 ). For the complexation reaction (using the Transition State Theory), the obtained values were: MeOH were ΔH ‡ 18,7 kcal/mol and ΔS ‡ 9,75 cal/K mol, while in EtOH, they were ΔH ‡ 23,0 kcal/mol and ΔS ‡ 24,9 cal/K mol. The experiments showed that the specific reaction rate increased when the permittivity was decreased and it was decreased when the ionic strength of the reaction medium was increased." @default.
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- W2185486581 date "2011-01-01" @default.
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- W2185486581 title "ESTUDIO TERMODINÁMICO Y CINÉTICO DE LA FORMACIÓN DEL COMPLEJO 2´(OH)ACETOFENONA-Al(III) THERMODYNAMIC AND KINETIC STUDY OF 2´(OH)ACETOPHENONE-Al(III) COMPLEX FORMATION" @default.
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