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- W2185966475 abstract "Macromolecules have been prepared containing native insulin carried by a modified insulin skeleton made by partially thio1ating the insulin hexamer and forming intermolecular cross-links through disu1phide bridges. Oxidation of partially thio1ated insulin (0.5 - 0.7 SH group/mole), formed by reacting insulin with AHTL, with, (a) potassium ferricyanide, (b) Cu++-oxygen gave water soluble macromolecules containing 20-26 and 410-708 monomer units respectively which had rod-random coil shape (light scattering). The larger molecules formed by (b) contained 8g-atom Cu++/hexamer unit and insulin. The insulin was firmly bound within the macromolecules and was probably bound within an insulin-modified insulin hexamer through coordination to copper." @default.
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- W2185966475 date "1977-01-01" @default.
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- W2185966475 title "MACROMOLECULES OF POTENTIAL THERAPEUTIC VALUE" @default.
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