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- W2186029604 abstract "A bimetallic complex Co II V IV L 2+ has been synthesized with binucleating macrocyclic ligand prepared by condensing 2 equiv. of 2,6-diformyl-4-methylphenol with 2 equiv. of 1,2-phenylenediamine. This has been immobilized by covalently binding it on a carbamate modified alumina support. The TGA analysis of the final catalyst shows that it is thermally stable up to 251 o C and it has been shown that it serves as an oxidation catalyst for n-octane oxidation. During the reaction, there is no change of molecular structure (i.e., absence of cracking or isomerization) and the four oxidative products are 2-octanone (1.5%), 3-octanone (1.2%), octanol (2.6%) and octanoic acid (0.5%) at 150°C. IPC: Int.Cl. 7 C 07 C 9/14" @default.
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- W2186029604 date "2005-02-01" @default.
- W2186029604 modified "2023-09-22" @default.
- W2186029604 title "Preparation of carbamate modified alumina supported heterobinuclear macrocyclic cobalt/vanadium complex for n -octane oxidation reaction" @default.
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