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- W2186042210 abstract "Chemical and spectroscopic characterization of fine particles fraction (< 1 μm) collected in the last stage (backup filter) of an Andersen impactor has been performed in flame and at t he exhaust of a 100 kW spray burner burning heavy fuel oils having a different content of asphaltenes and aromatics. The fine particulate was extracted in dichloromethane (DCM) for the analysis of soluble organic material by gas- chromatography-mass spectrometry (GC-MS), size exclusion chromatography (SEC) and UV-visible absorption and fluorescence. The residual particulate material insoluble in DCM was treated in a very polar and powerful solvent as N-methyl-pyrrolidone (NMP) that is able to dissolve and/or to get stable suspensions of soot, allowing their analysis by means of techniques generally applied only on liquid samples, as SEC and UV-visible absorption and fluorescence spectroscopy. SEC technique has allowed to evaluate a distribution of molecular masses and UV-visible a bsorption and fluorescence spectroscopy applied o n DCM and NMP solutions of samples allowed to investigate similarities and d ifferences in the c hemical structure and in particular on the aromaticity of the particulate materials collected in the smallest dimensional ranges (< 1μm)." @default.
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- W2186042210 date "2002-01-01" @default.
- W2186042210 modified "2023-09-30" @default.
- W2186042210 title "SIZING AND CHARACTERIZATION OF PARTICULATE EMISSIONS FROM HEAVY FUEL OIL SPRAY COMBUSTION" @default.
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