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• W2186314505 abstract "The physical properties of metal-ceramic composites are strongly affected by the local chemistry and atomic bonding across the interface. Information on both are contained in the energy-loss near-edge structure. The spectral component specific for the interface can be obtained by the spatial- difference technique. This method was applied for the investigation of two different interfaces, namely Al/Al2O3 and Cu/Al2O3. The Al-L2,3 edge at the Al/Al2O3 interface shows a characteristic energy-loss near-edge structure which was compared to multiple scattering calculations for Al(O3Al) tetrahedra with various Al-Al bond lengths. Good agreement with the experimental data was found for a cluster with an Al-Al bond length larger than the Al-O distance which is nearly that of amorphous Al2O3. No interface-specific component could be detected at the Al-L2,3 edge of the Cu/Al2O3 interface. However, the energy-loss near-edge structure of the Cu-L2,3 edge indicates that Cu exists at the interface in a Cu1+ state and that the chemical bond is established at the interface between Cu and O atoms." @default.
• W2186314505 created "2016-06-24" @default.
• W2186314505 creator A5006935322 @default.
• W2186314505 creator A5059019084 @default.
• W2186314505 date "1995-01-01" @default.
• W2186314505 modified "2023-09-24" @default.
• W2186314505 title "Electron Energy-Loss Near-Edge Structure of Metal-Alumina" @default.
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• W2186314505 hasPublicationYear "1995" @default.
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