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- W2186350087 abstract "For any isobaric invariant point on a fully expanded temperature versas mol fraction (T-X) phase diagram, there is a pair of phase assemblages whose stability fields span the largest divariant sectors on the low-T and high-T sides of the poinl and do not overlap along the T axis. The two assemblages have no solid phases in common, but together they include all the phases of the isobarically invariant assemblage. The closed-system reaction that relates these two assemblages produces a fluid phase of isobarically invariant composition, and it can be massbalanced algebraically without prior knowledge of the stable T-X topology, thus identifying the low-T and high-T phase assemblages in a simple and direct manner. These considerations justify and facilitate labeling of reactant and product assemblages on the polybailc P-T trace of any isobaric invariant point. In turn, such labeling facilitates direct chemographic expansion of H2O-CO2 or other mixed-volatile equilibria in P-T projection, bypassing the usual first step of constructing a complete set of stable T-X diagrams in the P range of interest. The resulting P-T phase diagrams are convenient in the determination and display of the P-T stability fields of silicate-carbonate mineral assemblages. Such diagrams also serve to identify critical subassemblages that are necessary and sufficient for rigorous mapping of isograds based on univariant mixed-volatile reactions and bathograds based on invariant mixed-volatile reactions." @default.
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- W2186350087 date "1991-12-01" @default.
- W2186350087 modified "2023-09-23" @default.
- W2186350087 title "Univariant mixed-volatile reactions; pressure-temperature phase diagrams and reaction isograds" @default.
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