Matches in SemOpenAlex for { <https://semopenalex.org/work/W2186551483> ?p ?o ?g. }
Showing items 1 to 81 of
81
with 100 items per page.
- W2186551483 endingPage "14" @default.
- W2186551483 startingPage "1" @default.
- W2186551483 abstract "A DFT modeling of the transition state of oxidative dehydrogenation of ethylbenzene over zirconium van adate catalyst has been carried out. Computations confir m a Mars-Van-Krevelen type redox mechanism in which the catalyst abstracts a hydrogen atom from the hydroca rbon and catalyst is reduced. The reduced catalyst is reoxidized by oxygen from air. Computations suggest t he formation of a hydroxyl species over the catalys t surface believed to have been formed due to abstraction of hydrogen atoms from ethyl benzene. A cyclic interme diate is formed which easily accepts one oxygen atom from ai r to regenerate the catalyst. The study shows that active species is vanadium and it follow a redox order of V=+5, V=+4, V=+3, V=+5." @default.
- W2186551483 created "2016-06-24" @default.
- W2186551483 creator A5011597177 @default.
- W2186551483 creator A5054050074 @default.
- W2186551483 creator A5059977069 @default.
- W2186551483 creator A5061406593 @default.
- W2186551483 creator A5080000379 @default.
- W2186551483 date "2014-01-01" @default.
- W2186551483 modified "2023-09-26" @default.
- W2186551483 title "A DFT study of oxidative dehydrogenation of ethyl benzene to styrene over zirconium vanadate catalyst" @default.
- W2186551483 hasPublicationYear "2014" @default.
- W2186551483 type Work @default.
- W2186551483 sameAs 2186551483 @default.
- W2186551483 citedByCount "0" @default.
- W2186551483 crossrefType "journal-article" @default.
- W2186551483 hasAuthorship W2186551483A5011597177 @default.
- W2186551483 hasAuthorship W2186551483A5054050074 @default.
- W2186551483 hasAuthorship W2186551483A5059977069 @default.
- W2186551483 hasAuthorship W2186551483A5061406593 @default.
- W2186551483 hasAuthorship W2186551483A5080000379 @default.
- W2186551483 hasConcept C119889771 @default.
- W2186551483 hasConcept C155647269 @default.
- W2186551483 hasConcept C15920480 @default.
- W2186551483 hasConcept C161790260 @default.
- W2186551483 hasConcept C178790620 @default.
- W2186551483 hasConcept C179104552 @default.
- W2186551483 hasConcept C185592680 @default.
- W2186551483 hasConcept C2777566558 @default.
- W2186551483 hasConcept C2777691172 @default.
- W2186551483 hasConcept C2779533485 @default.
- W2186551483 hasConcept C2781116636 @default.
- W2186551483 hasConcept C504678139 @default.
- W2186551483 hasConcept C521977710 @default.
- W2186551483 hasConcept C534791751 @default.
- W2186551483 hasConcept C55904794 @default.
- W2186551483 hasConcept C75473681 @default.
- W2186551483 hasConcept C94882840 @default.
- W2186551483 hasConceptScore W2186551483C119889771 @default.
- W2186551483 hasConceptScore W2186551483C155647269 @default.
- W2186551483 hasConceptScore W2186551483C15920480 @default.
- W2186551483 hasConceptScore W2186551483C161790260 @default.
- W2186551483 hasConceptScore W2186551483C178790620 @default.
- W2186551483 hasConceptScore W2186551483C179104552 @default.
- W2186551483 hasConceptScore W2186551483C185592680 @default.
- W2186551483 hasConceptScore W2186551483C2777566558 @default.
- W2186551483 hasConceptScore W2186551483C2777691172 @default.
- W2186551483 hasConceptScore W2186551483C2779533485 @default.
- W2186551483 hasConceptScore W2186551483C2781116636 @default.
- W2186551483 hasConceptScore W2186551483C504678139 @default.
- W2186551483 hasConceptScore W2186551483C521977710 @default.
- W2186551483 hasConceptScore W2186551483C534791751 @default.
- W2186551483 hasConceptScore W2186551483C55904794 @default.
- W2186551483 hasConceptScore W2186551483C75473681 @default.
- W2186551483 hasConceptScore W2186551483C94882840 @default.
- W2186551483 hasIssue "4" @default.
- W2186551483 hasLocation W21865514831 @default.
- W2186551483 hasOpenAccess W2186551483 @default.
- W2186551483 hasPrimaryLocation W21865514831 @default.
- W2186551483 hasRelatedWork W1597333855 @default.
- W2186551483 hasRelatedWork W1963934371 @default.
- W2186551483 hasRelatedWork W1967512934 @default.
- W2186551483 hasRelatedWork W1969684246 @default.
- W2186551483 hasRelatedWork W1971511255 @default.
- W2186551483 hasRelatedWork W1977502608 @default.
- W2186551483 hasRelatedWork W1978114782 @default.
- W2186551483 hasRelatedWork W1986589621 @default.
- W2186551483 hasRelatedWork W2001974313 @default.
- W2186551483 hasRelatedWork W2007769226 @default.
- W2186551483 hasRelatedWork W2015022747 @default.
- W2186551483 hasRelatedWork W2054051110 @default.
- W2186551483 hasRelatedWork W2062650421 @default.
- W2186551483 hasRelatedWork W2083960457 @default.
- W2186551483 hasRelatedWork W2149194854 @default.
- W2186551483 hasRelatedWork W236465687 @default.
- W2186551483 hasVolume "4" @default.
- W2186551483 isParatext "false" @default.
- W2186551483 isRetracted "false" @default.
- W2186551483 magId "2186551483" @default.
- W2186551483 workType "article" @default.