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- W2186578611 abstract "We proposed a new explanation of photo-induced volume changes in chalcogenide glasses. In our computer simulation we observed covalent bond breaking in the network caused by excited electrons, whereas holes contribute to the formation of inter-chain bonds. The interplay between photo-induced bond breaking and inter-chain bond formation leads to either volume expansion or shrinkage. In the non-ideal case, only a part of the processes is reversible and the total expansion includes the reversible and irreversible changes. Finally we investigate the structural properties of flatly and obliquely deposited chalcogenide thin films. Different void sizes can cause different photoinduced volume changes." @default.
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- W2186578611 date "2007-01-01" @default.
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- W2186578611 title "On photoinduced volume changes in chalcogenide glasses" @default.
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