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- W2186697046 abstract "Fixed mutual orientations of epitaxial crystals are preferably explained by the structure similarity. The process of such aggregate formation is usually discussed very schematically in terms of homogeneous or heterogeneous nucleation followed by a corrective turn to the epitaxial orientation but experimental evidences appear to be still unconvincing. The nature of a disoriented simultaneous growth of epitaxial crystals is not considered at all. Within the scope of this problem, regularities of oriented-disoriented deposition of grown or inactive crystals on a grown or dissolved seed were investigated in aqueous solutions mainly in connection with growth or dissolution kinetics. The behaviour of the epitaxial pairs KCl-NaCl, K2Cr2O7-KBr (grown deposit, grown or dissolved seed) and CaCO3 -NaNO3 (inactive deposit, grown seed) was examined. The two co-existing textures featured by a kinetics were observed: “epitaxial texture” of deposited crystals grown together by the similar planes but turned variously from the fixed position; “vertical texture” characterised by arbitrary angles (up to 90) between the similar planes of deposited and seed crystals. Additionally to the wellknown crystallochemical factor of the process, evidences of the two other factors were received: kinetic one (heterogeneous nucleation on a seed in the epitaxial position followed by an arbitrary disorientation of deposited crystals by growth layers) and adhesive one (attraction of homogeneously nucleated crystals by a seed accompanied by a corrective turn to the epitaxial orientation)." @default.
- W2186697046 created "2016-06-24" @default.
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- W2186697046 date "1999-01-01" @default.
- W2186697046 modified "2023-09-27" @default.
- W2186697046 title "DISORIENTATION EFFECTS OF EPITAXY AT AQUEOUS MEDIA" @default.
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