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- W2186744674 abstract "Detailed numerical calculations are compared against available experiments and are used to inveg tigate the flame suppression and extinction properties of a variety of flourinated hydrocarbon candidates selected for halon 1301 and halon 1211 replacement. The air stream in a methane vs. air counterflow diffusion flame is doped with varying amountsof ChF, CH2F2, CHF3, CF4, CHFz-CFs and CHzF-CF3, as well as the diluents N2 and COz, and their effect on the strain rate required for flame extinction is monitored. The chemical model is based on a recently developed set of thermochemical and chemical kinetic data for the C1 and Cz fluorinated hydrocarbons. Numerical results are in very good agreement with available experimental data for CF4- and CHF3suppresed methane vs. air counterflow diffusion flames. Both computations and experiments show similar linear decreases in required extinction strain rate with molar per cent agent added to the oxidizer stream, thereby yielding the same effectiveness for suppressing flames. The model and associated chemical kinetic mechanism and thermodynamic data base predict moderately lower extinction strain rates throughought the entire range of suppressant addition level, and calculations with alternate sets of C/H/O kineties are presented." @default.
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- W2186744674 date "1997-01-01" @default.
- W2186744674 modified "2023-09-27" @default.
- W2186744674 title "C1 AND Cz FLUORINATED HYDROCARBON EFFECTS ON THE EXTINCTION CHARACTERISTICS OF METHANE VS. AIR COUNTERFLOW DIFFUSION FLAMES" @default.
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