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- W2186942840 abstract "A mathematical model describing chemical kinetics of transesterification of model oil for biodiesel production has been developed. The model is based on the reverse mechanism of transesterification reactions and describes dynamics concentration changes of triglycerides, diglycerides, monoglycerides, biodiesel, and glycerol production. An analysis of process variables such as temperature and molar ratio model oil- methanol using response surface analysis was performed to achieve the maximum oil conversion rate to biodiesel. The reaction rate constants and activation energies were determined for all the forward and reverse reactions. The experimental results were found to fit a first-order kinetic law for the forward reaction and a second-order one for the reverse reaction. The results indicated that the rate-control step could be attributed to the surface reaction and the esterification processes can be well-depicted by the as-calculated kinetic formula in the range of the experimental conditions. A very good correlation between model simulations and experimental data was observed." @default.
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- W2186942840 date "2013-01-01" @default.
- W2186942840 modified "2023-09-23" @default.
- W2186942840 title "Kinetic study of used vegetable oil for esterification and transesterification process of biodiesel production" @default.
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