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- W2187318714 abstract "Transparent cubic-, tetragonal-zirconia thin films were successfully deposited on glass and quartz sub- strates by using the metalorganic chemical deposition technique. The thin films were achieved by adjusting deposition parameters such as substrate temperature, oxygen partial pressure, and zirconium acetylacetonate (Zr(acac)4) used as precursor. Structural and morphological character- izations of the as-deposited thin films were studied by XRD, Raman spectroscopy, SEM, and AFM techniques, while some optical properties such as transmittance and refractive index were determined by means of the UV-vis technique. The ZrO2 films, grown at 700 C and different PO2 :PZrðacacÞ4 ratios, displayed very variable particle sizes ranging from *0.2 to 1.0 lm, and crystallite sizes within 10-30 nm forming a uniform film. Low mean roughness was obtained in the samples, which varied from 0.674 to 1.33 nm. These films grew with a columnar structure and apparently with low carbon content (0.2%). All the synthesized thin films showed an adequate optical transmission, but the most transparent ((80%) was obtained with a PO2 :PZrðacacÞ4 ratio of (Pa) 107:0.2. The oxygen partial pressure influences the crystallinity of the as-deposited films, while the refractive index remains constant." @default.
- W2187318714 created "2016-06-24" @default.
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- W2187318714 date "2012-01-01" @default.
- W2187318714 modified "2023-09-27" @default.
- W2187318714 title "Characterization of ZrO 2 thin films deposited by MOCVD as ceramic coatings" @default.
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- W2187318714 hasPublicationYear "2012" @default.
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