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- W2187348568 abstract "CO 2 and N 2 adsorptions of alkali and alkaline earth metal cation exchanged zeolite L have been investigated by volumetric measurements and Grand Canonical Monte Carlo simulation. The zeolite KL shows lower degree of exchange because of its unique open-channel framework, linked cancrinite and intercage sites. Structural characteristics have been evaluated using X-ray diffraction analysis and surface area measurements. CO 2 and N 2 adsorption isotherms have been obtained for zeolite KL and its cation exchanged form up to 101.3 kPa at 293 and 303 K and the corresponding heats of adsorption estimated by the Clausius-Clapeyron equation. The experimental results are compared with those obtained from GCMC simulation. The texture of the materials and their selectivity for CO 2 over N 2 adsorption varies with the nature of the exchanged cations. Zeolite-CaL shows remarkably high CO 2 selectivity (31 times) over N 2 amongst the studied alkali and alkaline cation exchanged zeolite L. It has been shown that zeolite L can be used as a potential adsorbent for the removal of CO 2 from industrial effluent gases." @default.
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- W2187348568 date "2012-09-01" @default.
- W2187348568 modified "2023-09-23" @default.
- W2187348568 title "Adsorption selectivity of CO 2 over N 2 by cation exchanged zeolite L: Experimental and simulation studies" @default.
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