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- W2187560770 abstract "Copolymers of 2–hydroxyethyl methacrylate (E) and furfuryl acrylate (A) were prepared by free radical polymerization in toluene at 80°C using benzoyl peroxide as initiator. Copolymers were analyzed by 1 H–NMR in order to calculate the monomer composition in the copolymer. The monomer reactivity ratios were determined by four linear methods, Fineman–Ross, r1 = 1.33/r2 = 0.96; Fineman–Ross inverted, r1 = 1.27/r2 = 0.92; Kelen–Tudos, r1 = 1.3/r2 = 0.96 and Kelen–Tudos extended, r1 = 0.9982/r2 = 1.0004. Akaike Information Criterion was used to select the best r1–r2 pair of values. Dyads and triads confirm the average chain and copolymers type and lead to use a mathematical relationship to calculate a new r1–r2 par of values. The new values were r1 = 1.254/r2 = 1.08 from the dyads and r1 = 1.26/r2 = 1.07 from the triads. Other microstructure parameters such as run number (RN = 46.48, X = 1, one A units triads) and Q–e values for A, not reported before (e2 = 0.10 and Q2 = 1.68) were calculated. Copyright © 2013 VBRI press." @default.
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- W2187560770 date "2013-07-01" @default.
- W2187560770 modified "2023-09-27" @default.
- W2187560770 title "A New Statistical Point Of View To Choose A Better Linear Model For Reactivity And Microstructure Analysis In HEMA/Furfuryl Acrylate Copolymerization Process" @default.
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- W2187560770 doi "https://doi.org/10.5185/amlett.2012.10441" @default.
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