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- W2187580532 abstract "An iterative inversion procedure is used to obtain the effective isotropic part of the pair-interaction potential for some pure refrigerants from the proposed correlation function for the zero density collision integrals of viscosity. The Leonard-Jones (W12-6) potential energy function is used as the initial model potential required by the method. Over a range of reduced temperature extending from 1 to 100, this measured potential can be used in the calculation of the orientation-averaged viscosity collision integrals and the dimensionless ratios which are essential to calculate other transport properties. The thermophysical properties of gases, such as the density, heat capacity, viscosity and thermal conductivity, are important quantities in both science and engineering. From scientific point of view, the values of the properties are the manifestation of the microscopic motion and interactions of the molecules that comprise the gas. The properties are, therefore, intimately related to the forces that act between molecules in the gas. Thus, measurements of such properties can, in principle, be used to elucidate the quantitative and qualitative features of such forces. The relationship between the thermophysical properties of gases with the intermolecular potential and the ways in which the former have already been used to determine the latter for binary interactions for dilute gases, have received conspicuous attention. From engineering point of view, the knowledge of the thermophysical properties of gases, is a prerequisite for design of chemical plant process. However, the multiplicity of plants, process, gases and operating conditions means that it is impractical to meet the demand for properties by measurement alone. Hereby, it is mentioned that the relationships between transport properties of gases, especially viscosity, through intermolecular potential , can be employed to reduce the need for experimentation to a manageable level. The thermophysical properties of gases can be devided into two classes. The first class comprises the equilibrium properties of gases, which often determine the feasibility of a particular unit" @default.
- W2187580532 created "2016-06-24" @default.
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- W2187580532 date "2003-01-01" @default.
- W2187580532 modified "2023-09-24" @default.
- W2187580532 title "Pair interaction potential energy function for some practically important refrigerants from the viscosity in the limit of zero density" @default.
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