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- W2187615488 abstract "New azoiminato chelates of bivalent platinum, (HL 1 ) 2 Pt and (HL 2 ) 2 Pt, have been synthesized by the reaction of potassium tetrachloroplatinate with 2-(phenylazo)aniline (H 2 L 1 ) and 2-(p-tolylazo)aniline (H 2 L 2 ) respectively. The (HL 1 ) 2 Pt crystallises in a space group P2 1 /n. The bond parameters are in accordance with the formation of monoanionic azoiminato ligand. As a result of delocalisation in the ligand backbone, the phenyl ring adjacent to the chelate ring is distorted with four long and two short bonds. The UV-vis spectra of the complexes show intense charge transfer transitions at ∼750 nm. IR and 1 H NMR spectral data are consistent with amino proton dissociation from the ligand precursor. The cyclic voltammogram of the complexes exhibit two oxidative responses at potentials ∼ 0.5 V and ∼ 1.2 V vs SCE in dichloromethane-acetonitrile mixed solvent." @default.
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- W2187615488 date "2003-01-01" @default.
- W2187615488 modified "2023-09-27" @default.
- W2187615488 title "New azoiminato complexes of bivalent platinum: Syntheses, characterisation and structure" @default.
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