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- W2187844304 abstract "This paper addresses dioxin/furan formation issues in relation to the U.S. Department of Energy’s (DOE) thermal waste treatment system’s needs. The test objectives for the initial dioxin/furan tests were to measure the effect of particulate removal at various elevated operating temperatures on dioxin/furan formation, and to document the performance of the ceramic and high-efficiency particulate air (HEPA)-grade, sintered-metal filters. The first step in testing was to establish that dioxins/furans could indeed be produced under a given operating condition. The process conditions were then adjusted to meet the primary test objective. An appropriate test bed configuration was developed specifically for this test. A test process gas slipstream of nominally 2 pounds per minute (lb/min) was taken from a main process gas stream of nominally 8 lb/min. Test bed components included a ceramic hot filter in series with a sintered-metal, HEPA-grade filter downstream of a primary thermal waste treatment chamber and a natural gas afterburner. A plasma arc torch was used for the first test, which was run on two separate days, and a natural gas alternate thermal driver was used for the last four tests. The surrogate feed recipe was formulated for its ability to produce dioxins/furans, and to approximate DOE incinerator conditions when burned. The feedrate was adjusted to produce short periods (puffs) of reducing conditions to enhance dioxin/furan generation. Dioxin/furan sampling was accomplished by using the U.S. Environmental Protection Agency’s (EPA) Method 23, “Determination of Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans Emissions from Stationary Sources.” The test program was based on the hypothesis that dioxin/furan compounds form at 400 to 950 F in the presence of catalytically active solids, such as offgas particulate. It was expected that by filtering dioxin/furan formation-enhancing particulate at a temperature above the expected dioxin formation temperature, dioxin/furan formation could be retarded, if not eliminated, according to the specified process conditions. The work was performed by MSE Technology Applications, Inc. (MSE), in Butte, Montana, under the direction of the DOE’s Mixed Waste Focus Area (MWFA) and the DOE’s Western Environmental Technology Office (WETO)." @default.
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- W2187844304 date "1999-01-01" @default.
- W2187844304 modified "2023-09-26" @default.
- W2187844304 title "A STUDY OF DIOXIN AND FURAN FORMATION USING HOT FILTRATION FOR OFFGAS TREATMENT" @default.
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