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- W2187946490 abstract "Abstract The homeotypic compounds La 16.32 Ba 1.82 Sr 7.86 [Si 60 N 92.32 O 3.68 ]O 12 and La 13.68 Sr 12.32 [Si 60 N 96 ]F 6.32 O 5.68 were synthesized at high temperature (1600/1500 °C) in a radio‐frequency furnace. The crystal structures [ I $bar{4}$ m (no. 217), Z = 1, a = 13.3360(10)/13.3258(10) Å and V = 2371.8(5)/2366.4(5) Å 3 ] were solved and refined on basis of single‐crystal X‐ray diffraction data and were corroborated by lattice‐energy calculations (Madelung part of lattice energy, MAPLE) powder X‐ray diffraction data and FTIR spectroscopy. They consist of a three‐dimensional network of allside corner sharing SiN 4– x O x tetrahedra. The framework is characterized by double dreier rings. La 16.32 Ba 1.82 Sr 7.86 [Si 60 N 92.32 O 3.68 ]O 12 represents an oxonitridosilicate oxide and La 13.68 Sr 12.32 [Si 60 N 96 ]F 6.32 O 5.68 a nitridosilicate fluoride oxide, as the crystal structures contain non‐condensed (O [0] /O,F [0] ) anions. The first compound is isotypic to Sr 3 Ln 10 Si 18 Al 12 O 18 N 36 ( Ln = Ce, Pr, Nd; Z = 2), whereas the latter describes a disordered model of the crystal structure, which is homeotypic to the mentioned SiAlONs." @default.
- W2187946490 created "2016-06-24" @default.
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- W2187946490 date "2015-11-30" @default.
- W2187946490 modified "2023-10-09" @default.
- W2187946490 title "Lanthanum (Oxo)nitridosilicates: From Ordered to Disordered Crystal Structures" @default.
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- W2187946490 doi "https://doi.org/10.1002/zaac.201500730" @default.
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