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• W2187994906 abstract "Anion uptake and charge transport in a polymer of intrinsic microporosity (here PIM-EA-TB) is investigated for three cases: (i) the oxidation of ferrocene embedded into a thin film of PIM-EA-TB on a glassy carbon electrode, (ii) the reduction of protons absorbed into a thin film of PIM-EA-TB on a platinum electrode, and (iii) the potential-driven transport of anions and protons in an asymmetrically deposited free-standing PIM-EA-TB membrane working as a current rectifier or “ionic diode”. In all three cases the competing effects of the diameter and hydrophobicity (size and hydration energy) of the anion are important. For free-standing membranes very high ionic diode rectification ratios (> 103 at ± 1 V) are observed in particular for thicker deposits of PIM-EA-TB and for chloride or perchlorate containing electrolyte." @default.
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• W2187994906 date "2016-10-01" @default.
• W2187994906 modified "2023-09-29" @default.
• W2187994906 title "Polymers of intrinsic microporosity in electrochemistry: Anion uptake and transport effects in thin film electrodes and in free-standing ionic diode membranes" @default.
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• W2187994906 doi "https://doi.org/10.1016/j.jelechem.2015.11.038" @default.
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