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- W2188248921 abstract "An analysis on various catalysts was performed to determine their activities and selectivity for the nonHydrodesulphurization (Non-HDS) technique using diesel fuel. Catalysts studied included well characterized Silica-Alumina on Al2O3 and Activated Carbon supports, salt-acid supports, Organic Mesoporous Carbon, Woodcoat carbides, Mg/Mo/Zn oxide supported catalysts which were prepared by various reactions. The diesel fuel consists of 2-3.5 wt% of sulfur compounds (thiophene and dibenzothiophene) with approximate amounts of aliphatic, alkylaromatics and N-heterocyclic compounds. With oxygen as the oxidant and some metal oxides and adsorbents type catalyst are used in the oxidation-Adsorption reaction process reveals that the metal induced and adsorbent-oxide induced catalyst shows the best selectivity for oxidizing the S-heterocycles. Except for thiophene, there was only a small dependence of observed rates on catalyst ratio, temperature which suggests the reactions were partially diffusion controlled. The optimal catalyst (MoSil, Si-Al/Mo/Al2O3, and CsHPW-SiO2) showed high activity for conversion of Sheterocycles. This work includes further investigation of the better catalysts, full characterization of the products by GC-MS, ICP-AES to provide a hydrodynamic environment." @default.
- W2188248921 created "2016-06-24" @default.
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- W2188248921 date "2011-01-01" @default.
- W2188248921 modified "2023-09-27" @default.
- W2188248921 title "SELECTIVITY OF METAL, ADSORBENT, OXIDE, HETEROPOLYACID CATALYSTS FOR S-HETEROCYCLES DURING NON- HYDRODESULFURIZATION OF DIESEL FUEL" @default.
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