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• W2188374211 abstract "231 proposed a kinetic model, composed of the stages with participation of OPC from the model of Werner and Cool [lo], 79 reactions from the Twarowski mechanism (including reactions of phosphine oxidation with participation of PH,, PH,, PH), and several stages of interaction of CH, and CHI,O with phosphorus oxides. The rate constants of main Twarowski reactions have been modified including their dependencies from the temperature. Unfortunately, there are no published data on simulated structure of a flame doped with OPC using this model that could facilitate validation of the model by comparing the calculated data with experimental results. This model was applied only for calculation of burning velocities of stoichiometric CH,/air flame at a pressure of 1 bar. The investigations of Westbrook and co-workers [I 51 devoted to the development ofmechanisms of destruction and pyrolysis of OPC in flames are of great interest. This study is significant because the results of the calculation of thermochemical properties of OPC obtained using BAC-MP4 and PM3 codes are presented and compared with published data. The kinetic model ofDMMP and TMP destruction in a flame includes 202 reactions involving 41 phosphorus-containing species. At the same time the model takes into consideration practically all intermediates. Rate constants of many reactions are proposed by the authors. Rate constants of the reactions of the Twarowski mechanism have been modified. Comparison of calculated data obtained with a help of this model with experimental results on structure of subatmopheric H,/O, flame doped with DMMP and TMP demonstrated satisfactory agreement not only for stable flame species but also for labile phosphorus-containing species PO, PO,, HOPO and HOPO, [S,8]. The mechanism predicts the promoting effect of TMP and DMMP additives on HJO, flame stabilized on a flat burner at a pressure of 0.062 bar. In the work neither scheme of reactions in a flame nor rate constants are presented. Nevertheless, there is a reference [22] to the kinetic data on the web site." @default.
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• W2188374211 date "2001-01-01" @default.
• W2188374211 modified "2023-09-26" @default.
• W2188374211 title "EXPERIMENTAL STUDY AND MODELING OF THE EFFECT OF PHOSHORUS- CONTAINING COMPOUNDS ON PREMIXED ATMOSPHERIC METHANE-OXYGEN FLAME STRUCTURE AND PROPAGATION VELOCITY" @default.
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• W2188374211 hasPublicationYear "2001" @default.
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