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- W2188458804 abstract "Rosiaite occurs at the Cetine di Cotomiano mine, formerly named Rosia mine, associated with valen- tinite, tripuhyite, bindheimite and a phase corresponding to the synthetic B-Sb204 polymorph of cervantite. Rosiaite, appearing generally as aggregates of minute tabular {OOOl}crystals with hexagonal outline, is colour1ess to pale yellow, transparent, optically uniaxial negative and nonpleochroic with co=2.092(2) and I:: = 1.920(10). Microprobe analyses reveal a good compositional homogeneity and a quasi-ideal composition. The strongest lines in the powder pattern are dlOl = 3.49 A and dllO = 2.648 A. The crystal structure, described in the space group P3 1m with a = 5.295(1) A, c = 5.372(1) A and Z = 1, has been refined to R = 0.033, confirmingthe new mineral to be the natural analogue of synthetic PbSb206 studied previously. The approximately hexagonal close-packed structure of rosiaite shows a pattern of occupied octahedral sites identical to that of synthetic compounds such as Li:zZrF6, Li2MJOFs and several double hexaoxides, containing Sb or As." @default.
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- W2188458804 date "1996-01-01" @default.
- W2188458804 modified "2023-09-24" @default.
- W2188458804 title "Rosiaite, PbSb206, a new mineral from the Cetine mine, Siena, Italy" @default.
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