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- W2188694245 abstract "This study reports the sulfonated poly ether ether ketone/polypyrrole/aluminum phosphate nanocomposite as membrane for polymer electrolyte membrane fuel cell. Aluminum phosphate nanoparticles of average crystallite size ∼62 nm were synthesized by sol–gel method followed by calcination at 900 °C. The nanocomposite membranes were fabricated by immersing the sulfonated poly ether ether ketone film (with and without embedded aluminum phosphate nanoparticles) in pyrrole/methanol mixture followed by in-situ polymerization of absorbed pyrrole within the pores of support material. The membrane containing ∼4 wt% polypyrrole and 5 wt% aluminum phosphate showed ionic conductivity as high as 3.14 × 10−4 S cm−1. Approximately 68.8% reduction in water desorption rate was achieved in nanocomposite membrane compared to virgin sulfonated poly ether ether ketone. Membranes were thermally stable up to 300 °C and also exhibited low water and methanol uptake capacity that are favorable for direct methanol fuel cell application. Microstructure was examined by scanning electron microscope and correlated with the observed functional properties." @default.
- W2188694245 created "2016-06-24" @default.
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- W2188694245 date "2016-03-01" @default.
- W2188694245 modified "2023-09-30" @default.
- W2188694245 title "Superior water retention, ionic conductivity and thermal stability of sulfonated poly ether ether ketone/polypyrrole/aluminum phosphate nanocomposite based polymer electrolyte membrane" @default.
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- W2188694245 doi "https://doi.org/10.1016/j.jece.2015.11.033" @default.
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