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- W2188717811 abstract "The synthesis and X-ray structure of a six-coordinate (porphinato)iron(III) derivative having the mixed-axial ligation of perchlorate and dimethylformamide with no displacement of metal in a nonplanar porphyrinic environment is reported for the first time. The Fe-Np (Np: porphinato nitrogen) distances which range from 2.044(2) to 2.070(2) A, leaves little doubt that the Fe(III) ion is in high-spin state which is also supported by its characteristic axial EPR spectrum at low temperature. The axial Fe-O(DMF) distance is 2.050(2) A which is ~0.6 A shorter than the Fe-OClO 3 distance of the complex. In the complex, iron sits in the plane of four porphyrinic nitrogens even when metal coordinates to two non-equivalent axial ligands. The present study suggests that the displacement of iron in proteins is the consequence of non-equivalent axial coordination as well as the protein induced deformations at heme." @default.
- W2188717811 created "2016-06-24" @default.
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- W2188717811 date "2011-03-01" @default.
- W2188717811 modified "2023-09-27" @default.
- W2188717811 title "Synthesis, structure and properties of a high-spin Fe(III) porphyrin with non-equivalent axial ligands: Implications for the hemoproteins" @default.
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