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- W2188771749 abstract "Densities and viscosities of ethoxy ethanol (EEL) with n-butylamine (NBA), sec-butylamine (SBA), tert-butylamine (TBA), n-hexylamine (NHA), n-octylamine (NOA) and cyclohexylamine (CHA) have been measured at 308.15 K. Fromthe experimental data the excess volume (V E ), deviation in viscosity (η E ) and the excess molar Gibb's free energy of the activation of viscous flow (G* E ) have been computed and presented as function of composition. The parameter d' of the Grunberg and Nissan has been calculated. The observed variations of the properties for the above mixtures conclude that the interactions between unlike molecules predominate over the dissociation effects in the individual components. It is also evident that the presence of strong interactions between unlike molecules is predominant and characterized by the negative V E and positive η E , G* E and d 1 values. The excess volume, deviation in viscosity and excess molar Gibb's free energy of the activation of viscous flow have been fitted to Redlich-Kister equation to derive the coefficients and standard deviations." @default.
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- W2188771749 date "2004-09-01" @default.
- W2188771749 modified "2023-09-23" @default.
- W2188771749 title "Excess volume and viscosity of ethoxy ethanol with n-butylamine, sec-butylamine, tert-butylamine, n-hexylamine, n-octylamine and cyclohexylamine" @default.
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