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• W2189599863 abstract "Abstract The conjugate addition of hydroxylamines, oximes and hydroxamic acids provides convenient route to incorporate an NO moiety into various Michael acceptors. This chapter reviews comprehensive experimental reactions on the formation of carbon–nitrogen and carbon–oxygen bonds via conjugate addition of hydroxylamines, oximes and hydroxamic acids to alkenes, alkynes or allenes attached to one or more electron‐withdrawing groups. Hydroxylamine derivatives predominantly undergo N‐centered conjugate addition, while for the ambient nucleophilic oximes and hydroxamic acids, both N‐centered and O‐centered conjugate addition are operative by control of the reaction conditions. A concerted cycloaddition mechanism has been well established for the conjugate addition of N ‐substituted hydroxylamines. The last decade has witnessed enormous growth in enantioselective conjugate addition of hydroxylamine derivatives and the O‐centered oximes. General Introduction Conjugate Addition of Hydroxylamine and Itsderivatives Conjugate Addition of Oximes Conjugate Addition of Hydroxamic Acids Conclusions Acknowledgments" @default.
• W2189599863 created "2016-06-24" @default.
• W2189599863 creator A5039879900 @default.
• W2189599863 creator A5044143169 @default.
• W2189599863 creator A5064663421 @default.
• W2189599863 creator A5068638985 @default.
• W2189599863 date "2010-09-15" @default.
• W2189599863 modified "2023-10-12" @default.
• W2189599863 title "Conjugate Addition of Hydroxylamines, Oximes and Hydroxamic Acids" @default.
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