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- W2189773436 abstract "The quaternary chalcohalide Ba4Sb3S8Cl has been prepared from stoichiometric mixtures of BaCl2, Ba, Sb, and S at 1093 K in an evacuated silica tube. Ba4Sb3S8Cl crystallizes in the monoclinic P21/c space group and features a 0D structure containing totally isolated [SbS3]3− units and discrete SbS2Cl trigonal pyramids separated by Ba2+ cations. The [SbS3]3− units and SbS2Cl trigonal pyramids are further packed in a pseudolayer motif in bc plane, respectively. The [SbS3]3− units are built by dimeric Sb2S6 polyhedras and SbS3 trigonal pyramids. Within the dimeric Sb2S6 polyhedra, two SbS4 seesaws share edges, while two SbS3 trigonal pyramids share corners with dimeric Sb2S6 polyhedra. The optical gap of 2.09 eV for Ba4Sb3S8Cl was deduced from the UV/Vis reflectance spectroscopy." @default.
- W2189773436 created "2016-06-24" @default.
- W2189773436 creator A5022469389 @default.
- W2189773436 date "2016-03-01" @default.
- W2189773436 modified "2023-10-09" @default.
- W2189773436 title "Synthesis, crystal structure, and optical property of the quaternary chalcohalide Ba4Sb3S8Cl" @default.
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- W2189773436 doi "https://doi.org/10.1016/j.jssc.2015.12.004" @default.
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