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• W2190131830 endingPage "11882" @default.
• W2190131830 startingPage "11875" @default.
• W2190131830 abstract "Five new lanthanide molybdenum oxides containing mixed valent Mo(IV/V) rutile-like chains, Ln5Mo2O12 Ln = Eu, Tb, Dy, Ho, and Er, were prepared utilizing a high-temperature molten salt flux synthesis involving an in situ reduction utilizing metallic reducing agents. All five compounds were structurally characterized by single-crystal and powder X-ray diffraction methods and were found to crystallize in the monoclinic space group C2/m. The molybdates all contain rare infinite chains consisting of MoO2O4/2 edge-sharing octahedra. The chains exhibit alternating long and short separations between octahedra caused by the presence of Mo-Mo bonds to form Mo2O10 units containing one unpaired electron. The temperature dependence of the magnetic susceptibility of these compounds was measured, and antiferromagnetic ordering was observed in all cases." @default.
• W2190131830 created "2016-06-24" @default.
• W2190131830 creator A5010999034 @default.
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• W2190131830 date "2015-12-02" @default.
• W2190131830 modified "2023-10-03" @default.
• W2190131830 title "High-Temperature Salt Flux Crystal Growth of New Lanthanide Molybdenum Oxides, Ln₅Mo₂O₁₂ Ln = Eu, Tb, Dy, Ho, and Er: Magnetic Coupling within Mixed Valent Mo(IV/V) Rutile-Like Chains" @default.
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• W2190131830 doi "https://doi.org/10.1021/acs.inorgchem.5b02132" @default.
• W2190131830 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26629588" @default.
• W2190131830 hasPublicationYear "2015" @default.
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