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- W2191036609 abstract "Abstract The highly accurate (experimental accuracy in line positions ∼ ( 1 - 2 ) × 10 - 4 cm−1) ro-vibrational spectrum of the ν 8 + ν 10 band of the 12C2H4 molecule was recorded for the first time with high resolution Fourier transform spectrometry and analyzed in the region of 1650–1950 cm−1 using the Hamiltonian model which takes into account Coriolis resonance interactions between the studied ν 8 + ν 10 band, which is forbidden in absorption, and the bands ν 4 + ν 8 and ν 7 + ν 8 . About 1570 transitions belonging to the ν 8 + ν 10 band were assigned in the experimental spectra with the maximum values of quantum numbers J max . = 35 and K a max . = 18 . On that basis, a set of 38 vibrational, rotational, centrifugal distortion, and resonance interaction parameters was obtained from the fit. They reproduce values of 598 initial “experimental” ro-vibrational energy levels (positions of about 1570 experimentally recorded and assigned transitions) with the rms error d rms = 0.00045 cm−1 ( d rms = 0.00028 cm−1 when upper ro-vibrational energies obtained from blended and very weak transitions were deleted from the fit)." @default.
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- W2191036609 date "2015-07-01" @default.
- W2191036609 modified "2023-10-15" @default.
- W2191036609 title "Precise ro-vibrational analysis of molecular bands forbidden in absorption: The <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si167.gif overflow=scroll><mml:mrow><mml:msub><mml:mrow><mml:mi>ν</mml:mi></mml:mrow><mml:mrow><mml:mn>8</mml:mn></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mrow><mml:mi>ν</mml:mi></mml:mrow><mml:mrow><mml:mn>10</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math> band of the 12C2H4 molecule" @default.
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- W2191036609 doi "https://doi.org/10.1016/j.jms.2015.04.008" @default.
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