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- W2192989405 abstract "The functional resin poly-MTEMA–DMAA–MBA (MTEMA, 2-(methylthio)ethylmethacrylate; 4 mol%, DMAA, N,N-dimethylacrylamide, 88 mol%; MBA, N,N’-methylenebisacrylamide, 8 mol%) referred to as MTEMA–DMAA-4–8, behaves as a macromolecular ligand towards PdII and AuIII in water (Pd) and acetonitrile (Au). Mn/resin complexes are easily reduced with NaBH4 in water to M0/resin composites. The swollen polymer framework of MTEMA–DMAA-4–8 is seen to act as a “mold” leading to the production of ca. 2.5 nm nanoclusters for both elements. M0/MTEMA–DMAA-4–8 composites exhibit useful catalytic properties in various chemical transformations, under mild conditions in water." @default.
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- W2192989405 date "2005-01-01" @default.
- W2192989405 modified "2023-09-27" @default.
- W2192989405 title "Generation of size-controlled gold(0) and palladium(0) nanoclusters inside the nanoporous domains of gel-type functional resins" @default.
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- W2192989405 doi "https://doi.org/10.1016/j.molcata.2004.08.042" @default.
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