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- W2193077148 abstract "The reactions of Cd(OAc)2·2H2O with variously substituted pyridines in methanol afforded unique one-dimensional coordination polymers (1D CPs), [Cd2(μ2-κ2:κ1-OAc)2(μ2-κ1:κ1-OAc)2L2] (L = NC5H5 (1), NC5H4Me-3 (2), and NC5H3Me2-3,5 (3)) and [Cd3(μ3-κ1:κ2-OAc)3(μ2-κ2-OAc)(μ2-κ2:κ1-OAc)2(NC5H3Me2-3,4)2] (4), and discrete and bimolecular complexes, [(Cd(OAc)2(NC5H3Me2-3,4)2(H2O)2] (5), [Cd(κ2-OAc)2(NC5H4Me-4)2(H2O)]·[Cd(κ2-OAc)2(H2O)2)] (6), [Cd(κ2-OAc)2L2L′]·xH2O (x = 0, L′ = H2O, L = NC5H4(OMe)-4 (7); NC5H4tBu-4 (8); x = 2, L = L′ = NC5H4(NMe2)-4 (9·2H2O)). The products were characterised by elemental analysis, IR, solution NMR (1H and 13C), solid-state CP-MAS 13C{1H} and 113Cd NMR, TGA/DTA analyses, and single crystal X-ray diffraction. Phase purity of 1–4 was verified by powder X-ray diffraction (PXRD). Plausible mechanisms of formation of the products are proposed based on a point zero charge model. 4 represents the first cadmium containing 1D CP that possesses a tridentate bridging (μ3-κ1:κ2) acetate coordination mode and 6 represents the first structurally characterised bimolecular cadmium(II) complex containing two different neutral cadmium(II) coordination species per formula unit. 9·2H2O was calcined at 500 °C to afford CdO as confirmed by PXRD and the morphology of CdO was studied by scanning electron microscopy." @default.
- W2193077148 created "2016-06-24" @default.
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- W2193077148 date "2015-09-01" @default.
- W2193077148 modified "2023-10-02" @default.
- W2193077148 title "Reactions of Cd(OAc)2·2H2O with variously substituted pyridines. Efforts to unravel the factors that determine structure/nuclearity of the products" @default.
- W2193077148 cites W1409974049 @default.
- W2193077148 cites W1965614166 @default.
- W2193077148 cites W1966474385 @default.
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- W2193077148 cites W1970556361 @default.
- W2193077148 cites W1973201734 @default.
- W2193077148 cites W1977714814 @default.
- W2193077148 cites W1978928219 @default.
- W2193077148 cites W1983656299 @default.
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- W2193077148 cites W1989286143 @default.
- W2193077148 cites W1992238598 @default.
- W2193077148 cites W1993408779 @default.
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- W2193077148 cites W1997512118 @default.
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- W2193077148 cites W2014286734 @default.
- W2193077148 cites W2015108171 @default.
- W2193077148 cites W2018535202 @default.
- W2193077148 cites W2020693802 @default.
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- W2193077148 cites W2036321927 @default.
- W2193077148 cites W2039738819 @default.
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- W2193077148 cites W2042357040 @default.
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- W2193077148 doi "https://doi.org/10.1016/j.poly.2015.06.002" @default.
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