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- W2193114590 abstract "A series of organic–inorganic alkaline hybrid membranes were prepared based on crosslinked quaternized chitosan (QCS, the quaternization degree (DQ) was 63.5(± 2.5)%) with different contents of tetrabutyl titanate (TBT) for alkaline direct methanol fuel cells (ADMFCs). The result revealed that the obtained anion exchange membranes (AEMs) were stable up to 150.0 °C in the air atmosphere according to the TGA analysis and anionic conductivities of the hybrid membranes at a level of 10− 2 S cm− 1 were obtained at 70.0 °C. A tensile stress at a break of 41.19 MPa at room temperature was achieved for QCS-TBT20% membrane. The anionic conductivity of QCS-TBTx% (15 ≤ X ≤ 25) membrane in 1.0 mol L− 1 KOH solution was stable for more than 60.0 h. Corresponding to the increase in the content of TBT from 0 wt.% to 25 wt.% in the hybrid membrane, the methanol permeability was decreased from 7.55 × 10− 6 cm2 s− 1 to 1.85 × 10− 6 cm2 s− 1. The water swelling of QCS-TBTx% (X ≤ 30) membranes was discussed based on the stress relaxation model of polymer chains, and it obeyed the Schott's second-order swelling kinetics." @default.
- W2193114590 created "2016-06-24" @default.
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- W2193114590 date "2015-12-01" @default.
- W2193114590 modified "2023-10-18" @default.
- W2193114590 title "Alkaline hybrid composite membrane for direct methanol fuel cells application" @default.
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- W2193114590 doi "https://doi.org/10.1016/j.jelechem.2015.11.012" @default.
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