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• W2193139268 abstract "Nitrobenzene (NB) would undergo photodegradation in sunlit surface waters, mainly by direct photolysis and triplet-sensitized oxidation, with a secondary role of the OH reaction. Its photochemical half-life time would range from a few days to a couple of months under fair-weather summertime irradiation, depending on water chemistry and depth. NB phototransformation gives phenol and the three nitrophenol isomers, in different yields depending on the considered pathway. The minor OH role in degradation would make NB unsuitable as OH probe in irradiated natural water samples, but the selectivity towards OH could be increased by monitoring the formation of phenol from NB+OH. The relevant reaction would proceed through ipso-addition of OH on the carbon atom bearing the nitro-group, forming a pre-reactive complex that would evolve into a transition state (and then into a radical addition intermediate) with very low activation energy barrier." @default.
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• W2193139268 date "2016-02-01" @default.
• W2193139268 modified "2023-10-17" @default.
• W2193139268 title "Modeling the photochemical transformation of nitrobenzene under conditions relevant to sunlit surface waters: Reaction pathways and formation of intermediates" @default.
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• W2193139268 doi "https://doi.org/10.1016/j.chemosphere.2015.11.039" @default.
• W2193139268 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26688265" @default.
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