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• W2194734605 abstract "In this paper a generalization of the Cahn-Hilliard theory of binary liquids is presented for multi-component incompressible liquid mixtures. First, a thermodynamically consistent convection-diffusion type dynamics is derived on the basis of the Lagrange multiplier formalism. Next, a generalization of the binary Cahn-Hilliard free energy functional is presented for arbitrary number of components, offering the utilization of independent pairwise equilibrium interfacial properties. We show that the equilibrium two-component interfaces minimize the functional, and demonstrate, that the energy penalization for multi-component states increases strictly monotonously as a function of the number of components being present. We validate the model via equilibrium contact angle calculations in ternary and quaternary (4-component) systems. Simulations addressing liquid flow assisted spinodal decomposition in these systems are also presented." @default.
• W2194734605 created "2016-06-24" @default.
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• W2194734605 date "2016-01-25" @default.
• W2194734605 modified "2023-10-17" @default.
• W2194734605 title "Phase-field theory of multicomponent incompressible Cahn-Hilliard liquids" @default.
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• W2194734605 doi "https://doi.org/10.1103/physreve.93.013126" @default.
• W2194734605 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26871173" @default.
• W2194734605 hasPublicationYear "2016" @default.
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