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• W2194911443 abstract "In an attempt to develop new coloured inorganic oxides, we have investigated the substitution of 3d transition-metal ions in LiMgBO3 host [where MgII has a trigonal bipyramidal (TBP) oxygen coordination]. We find that single-phase materials are formed for LiMg1–xCoIIxBO3 (0 < x ≤ 1.0), LiMg1–xNiIIxBO3 (0 < x ≤ 0.1), LiMg1–xCuIIxBO3 (0 < x ≤ 0.1) and also Li1–xMg1–xFeIIIxBO3 (0 < x ≤ 0.1) of which the CoII and NiII derivatives are strongly coloured, purple-blue and beige-red, respectively, thus identifying TBP CoO5 and NiO5 as new chromophores for these colours." @default.
• W2194911443 created "2016-06-24" @default.
• W2194911443 creator A5010877741 @default.
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• W2194911443 creator A5074181166 @default.
• W2194911443 creator A5083780166 @default.
• W2194911443 date "2015-12-11" @default.
• W2194911443 modified "2023-10-16" @default.
• W2194911443 title "Exploring the Colour of 3d Transition‐Metal Ions in Trigonal Bipy­ramidal Coordination: Identification of Purple‐Blue (CoO ₅ ) and Beige‐Red (NiO ₅ ) Chromophores in LiMgBO ₃ Host" @default.
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• W2194911443 doi "https://doi.org/10.1002/ejic.201501064" @default.
• W2194911443 hasPublicationYear "2015" @default.
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