Matches in SemOpenAlex for { <https://semopenalex.org/work/W2196181375> ?p ?o ?g. }
- W2196181375 endingPage "2097" @default.
- W2196181375 startingPage "2090" @default.
- W2196181375 abstract "Detailed numerical analysis of literature data for five key thermodynamic properties (activity coefficients, osmotic coefficients, apparent molar relative enthalpies, heat capacities, and volumes) of well-characterized aqueous strong electrolyte solutions shows that equally good fits are generally obtained from the Pitzer and Huckel equations when both frameworks have the same number of adjustable parameters. Fifty-seven strong electrolyte systems with published values at 25 °C have been examined: the differences found between the two frameworks are never large and are only significant with the activity and osmotic coefficients of eight systems. Most of these eight exceptions involve a lanthanide salt that has been characterized by just one research group. For describing the solution thermodynamics of binary (single) strong electrolytes, the Pitzer equations are found to possess no fundamental theoretical advantage over an extended Huckel framework. On the other hand, slight additional flexibility inherent in the Pitzer formalism makes it more susceptible than the Huckel equations to the numerical effects of experimental error. Comparing the fits achieved by the Pitzer and Huckel equation frameworks can help to identify (a) the simple behavior characteristic of strong electrolytes even at high concentration and (b) signs of error in experimental data sets lacking confirmation by independent measurement." @default.
- W2196181375 created "2016-06-24" @default.
- W2196181375 creator A5017148181 @default.
- W2196181375 creator A5052481063 @default.
- W2196181375 date "2015-06-16" @default.
- W2196181375 modified "2023-09-25" @default.
- W2196181375 title "Comparison of the Pitzer and Hückel Equation Frameworks for Activity Coefficients, Osmotic Coefficients, and Apparent Molar Relative Enthalpies, Heat Capacities, and Volumes of Binary Aqueous Strong Electrolyte Solutions at 25 °C" @default.
- W2196181375 cites W1978568707 @default.
- W2196181375 cites W1981603113 @default.
- W2196181375 cites W1985324387 @default.
- W2196181375 cites W1989856923 @default.
- W2196181375 cites W1994461954 @default.
- W2196181375 cites W2003606762 @default.
- W2196181375 cites W2009566462 @default.
- W2196181375 cites W2012630590 @default.
- W2196181375 cites W2014549965 @default.
- W2196181375 cites W2016702199 @default.
- W2196181375 cites W2028178847 @default.
- W2196181375 cites W2028976886 @default.
- W2196181375 cites W2029737158 @default.
- W2196181375 cites W2030407731 @default.
- W2196181375 cites W2030947318 @default.
- W2196181375 cites W2033432298 @default.
- W2196181375 cites W2035123790 @default.
- W2196181375 cites W2035695555 @default.
- W2196181375 cites W2036414031 @default.
- W2196181375 cites W2038167037 @default.
- W2196181375 cites W2039763530 @default.
- W2196181375 cites W2040842494 @default.
- W2196181375 cites W2041672759 @default.
- W2196181375 cites W2043228164 @default.
- W2196181375 cites W2046141875 @default.
- W2196181375 cites W2049967220 @default.
- W2196181375 cites W2050332057 @default.
- W2196181375 cites W2053958948 @default.
- W2196181375 cites W2055209099 @default.
- W2196181375 cites W2057006525 @default.
- W2196181375 cites W2057545160 @default.
- W2196181375 cites W2059198863 @default.
- W2196181375 cites W2074642780 @default.
- W2196181375 cites W2077516107 @default.
- W2196181375 cites W2079044367 @default.
- W2196181375 cites W2082523876 @default.
- W2196181375 cites W2083612741 @default.
- W2196181375 cites W2086249756 @default.
- W2196181375 cites W2090988778 @default.
- W2196181375 cites W2100350565 @default.
- W2196181375 cites W2140376244 @default.
- W2196181375 cites W2147416714 @default.
- W2196181375 cites W2157691763 @default.
- W2196181375 cites W2159560648 @default.
- W2196181375 cites W2314238492 @default.
- W2196181375 cites W2316532134 @default.
- W2196181375 cites W2317177648 @default.
- W2196181375 cites W2321497514 @default.
- W2196181375 cites W2329976913 @default.
- W2196181375 cites W2331709034 @default.
- W2196181375 cites W2412200685 @default.
- W2196181375 cites W244283745 @default.
- W2196181375 cites W2516059355 @default.
- W2196181375 cites W2615525674 @default.
- W2196181375 cites W28004727 @default.
- W2196181375 cites W4230874833 @default.
- W2196181375 cites W4242807495 @default.
- W2196181375 cites W4252608207 @default.
- W2196181375 cites W4253679891 @default.
- W2196181375 cites W4254928932 @default.
- W2196181375 cites W610861889 @default.
- W2196181375 cites W4298029051 @default.
- W2196181375 doi "https://doi.org/10.1021/acs.jced.5b00161" @default.
- W2196181375 hasPublicationYear "2015" @default.
- W2196181375 type Work @default.
- W2196181375 sameAs 2196181375 @default.
- W2196181375 citedByCount "10" @default.
- W2196181375 countsByYear W21961813752017 @default.
- W2196181375 countsByYear W21961813752018 @default.
- W2196181375 countsByYear W21961813752019 @default.
- W2196181375 countsByYear W21961813752020 @default.
- W2196181375 countsByYear W21961813752022 @default.
- W2196181375 crossrefType "journal-article" @default.
- W2196181375 hasAuthorship W2196181375A5017148181 @default.
- W2196181375 hasAuthorship W2196181375A5052481063 @default.
- W2196181375 hasConcept C121332964 @default.
- W2196181375 hasConcept C129396204 @default.
- W2196181375 hasConcept C147789679 @default.
- W2196181375 hasConcept C170961132 @default.
- W2196181375 hasConcept C17525397 @default.
- W2196181375 hasConcept C182899088 @default.
- W2196181375 hasConcept C184651966 @default.
- W2196181375 hasConcept C185592680 @default.
- W2196181375 hasConcept C199343813 @default.
- W2196181375 hasConcept C202271784 @default.
- W2196181375 hasConcept C3288061 @default.
- W2196181375 hasConcept C35249275 @default.
- W2196181375 hasConcept C68801617 @default.
- W2196181375 hasConcept C71924100 @default.
- W2196181375 hasConcept C88371329 @default.
- W2196181375 hasConcept C97355855 @default.