Matches in SemOpenAlex for { <https://semopenalex.org/work/W2196248082> ?p ?o ?g. }
- W2196248082 endingPage "210" @default.
- W2196248082 startingPage "204" @default.
- W2196248082 abstract "The enthalpies of solution, solvation and vaporization/sublimation are interrelated values combined in the simplest thermodynamic circle. Hence, experimental determination of vaporization/sublimation enthalpy can be substituted by experimentally simpler determination of solution enthalpy when solvation enthalpy is known. Previously it was found that solvation enthalpies of a wide range of unbranched aliphatic and aromatic solutes in saturated hydrocarbons are in good linear correlation with their molar refraction values. This allows to estimate the vaporization/sublimation enthalpy of any unbranched organic compound from its solution enthalpy in saturated hydrocarbon and molar refraction. In the present work this approach was modified for determination of vaporization/sublimation enthalpy of branched-chain alkyl aromatic and aliphatic compounds. Group contributions to the enthalpy of solvation due to the branching of carbon chain were evaluated. Enthalpies of solution at infinite dilution of 18 branched-chain aliphatic and alkyl aromatic compounds were measured at T = 298.15 K. Vaporization/sublimation enthalpies for 35 branched aliphatic and alkyl aromatic compounds were determined by using modified solution calorimetry approach. These values are in good agreement with available literature data on vaporization/sublimation enthalpies obtained by conventional methods." @default.
- W2196248082 created "2016-06-24" @default.
- W2196248082 creator A5012914269 @default.
- W2196248082 creator A5019002975 @default.
- W2196248082 creator A5054580908 @default.
- W2196248082 creator A5055961408 @default.
- W2196248082 date "2015-12-01" @default.
- W2196248082 modified "2023-10-16" @default.
- W2196248082 title "Modified solution calorimetry approach for determination of vaporization and sublimation enthalpies of branched-chain aliphatic and alkyl aromatic compounds at T= 298.15 K" @default.
- W2196248082 cites W1971948599 @default.
- W2196248082 cites W1975200744 @default.
- W2196248082 cites W1975676801 @default.
- W2196248082 cites W1980564890 @default.
- W2196248082 cites W1992863525 @default.
- W2196248082 cites W2036174459 @default.
- W2196248082 cites W2036373158 @default.
- W2196248082 cites W2038373650 @default.
- W2196248082 cites W2042140728 @default.
- W2196248082 cites W2044473188 @default.
- W2196248082 cites W2052271061 @default.
- W2196248082 cites W2056226320 @default.
- W2196248082 cites W2065797426 @default.
- W2196248082 cites W2072580653 @default.
- W2196248082 cites W2085758254 @default.
- W2196248082 cites W2088240214 @default.
- W2196248082 cites W2094109929 @default.
- W2196248082 cites W2106243370 @default.
- W2196248082 cites W2153068384 @default.
- W2196248082 cites W2154208755 @default.
- W2196248082 cites W2155136476 @default.
- W2196248082 cites W2333785381 @default.
- W2196248082 cites W2334282424 @default.
- W2196248082 cites W2949329052 @default.
- W2196248082 cites W2949364446 @default.
- W2196248082 cites W4245647988 @default.
- W2196248082 doi "https://doi.org/10.1016/j.jct.2015.07.037" @default.
- W2196248082 hasPublicationYear "2015" @default.
- W2196248082 type Work @default.
- W2196248082 sameAs 2196248082 @default.
- W2196248082 citedByCount "29" @default.
- W2196248082 countsByYear W21962480822015 @default.
- W2196248082 countsByYear W21962480822016 @default.
- W2196248082 countsByYear W21962480822017 @default.
- W2196248082 countsByYear W21962480822018 @default.
- W2196248082 countsByYear W21962480822019 @default.
- W2196248082 countsByYear W21962480822020 @default.
- W2196248082 countsByYear W21962480822021 @default.
- W2196248082 countsByYear W21962480822022 @default.
- W2196248082 crossrefType "journal-article" @default.
- W2196248082 hasAuthorship W2196248082A5012914269 @default.
- W2196248082 hasAuthorship W2196248082A5019002975 @default.
- W2196248082 hasAuthorship W2196248082A5054580908 @default.
- W2196248082 hasAuthorship W2196248082A5055961408 @default.
- W2196248082 hasConcept C121332964 @default.
- W2196248082 hasConcept C129564387 @default.
- W2196248082 hasConcept C132704077 @default.
- W2196248082 hasConcept C13530604 @default.
- W2196248082 hasConcept C147368240 @default.
- W2196248082 hasConcept C147789679 @default.
- W2196248082 hasConcept C148093993 @default.
- W2196248082 hasConcept C15744967 @default.
- W2196248082 hasConcept C178790620 @default.
- W2196248082 hasConcept C185592680 @default.
- W2196248082 hasConcept C190204305 @default.
- W2196248082 hasConcept C195801359 @default.
- W2196248082 hasConcept C202270520 @default.
- W2196248082 hasConcept C2780263894 @default.
- W2196248082 hasConcept C3288061 @default.
- W2196248082 hasConcept C32909587 @default.
- W2196248082 hasConcept C542102704 @default.
- W2196248082 hasConcept C58437636 @default.
- W2196248082 hasConcept C60778519 @default.
- W2196248082 hasConcept C97355855 @default.
- W2196248082 hasConceptScore W2196248082C121332964 @default.
- W2196248082 hasConceptScore W2196248082C129564387 @default.
- W2196248082 hasConceptScore W2196248082C132704077 @default.
- W2196248082 hasConceptScore W2196248082C13530604 @default.
- W2196248082 hasConceptScore W2196248082C147368240 @default.
- W2196248082 hasConceptScore W2196248082C147789679 @default.
- W2196248082 hasConceptScore W2196248082C148093993 @default.
- W2196248082 hasConceptScore W2196248082C15744967 @default.
- W2196248082 hasConceptScore W2196248082C178790620 @default.
- W2196248082 hasConceptScore W2196248082C185592680 @default.
- W2196248082 hasConceptScore W2196248082C190204305 @default.
- W2196248082 hasConceptScore W2196248082C195801359 @default.
- W2196248082 hasConceptScore W2196248082C202270520 @default.
- W2196248082 hasConceptScore W2196248082C2780263894 @default.
- W2196248082 hasConceptScore W2196248082C3288061 @default.
- W2196248082 hasConceptScore W2196248082C32909587 @default.
- W2196248082 hasConceptScore W2196248082C542102704 @default.
- W2196248082 hasConceptScore W2196248082C58437636 @default.
- W2196248082 hasConceptScore W2196248082C60778519 @default.
- W2196248082 hasConceptScore W2196248082C97355855 @default.
- W2196248082 hasFunder F4320321079 @default.
- W2196248082 hasFunder F4320321912 @default.
- W2196248082 hasFunder F4320327643 @default.
- W2196248082 hasLocation W21962480821 @default.
- W2196248082 hasOpenAccess W2196248082 @default.