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• W2196323193 abstract "Neutron diffraction measurements were performed to investigate the structure of SbxSe100−x bulk glasses with x=5, 10, 15, 20 and 25 at% Sb. The total pair distribution functions show two peaks at 2.36 Å and 2.64 Å, which are attributed to Se–Se and Sb–Se bonds, respectively. The coordination numbers calculated from these peaks indicate that Sb atoms are three-coordinated and Se atoms are two-coordinated for all the above compositions. However, the composition dependences of the first two peaks in the structure factors show an obvious change between 15 and 20 at% Sb, indicating that the medium-range structure is changed in this range of Sb content. In order to elucidate the medium-range structure, reverse Monte Carlo simulation was used with coordination number constraints. The structure models consisting of a mixture of the SbSe3/2 network and Sen chain clusters were in good agreement with neutron diffraction data for Se-rich glass (5, 10 and 15 at% Sb). On the other hand, a better fit was obtained for Sb25Se75 glass with a model based on the network structure formed by connected SbSe3 units." @default.
• W2196323193 created "2016-06-24" @default.
• W2196323193 creator A5086511931 @default.
• W2196323193 date "2016-01-01" @default.
• W2196323193 modified "2023-10-18" @default.
• W2196323193 title "Short- and medium-range order in Sb–Se glasses" @default.
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• W2196323193 doi "https://doi.org/10.1016/j.jssc.2015.11.018" @default.
• W2196323193 hasPublicationYear "2016" @default.
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