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• W2196604285 abstract "We present a quintuple-mode operator-based Floquet approach to describe arbitrary amplitude modulated cross polarization experiments under magic-angle spinning (MAS). The description is used to analyze variants of the RESPIRATION approach (RESPIRATIONCP) where recoupling conditions and the corresponding first-order effective Hamiltonians are calculated, validated numerically and compared to experimental results for 15N-13C coherence transfer in uniformly 13C,15N-labeled alanine and in uniformly 2H,13C,15N-labeled (deuterated and 100% back-exchanged) ubiquitin at spinning frequencies of 16.7 and 90.9 kHz. Similarities and differences between different implementations of the RESPIRATIONCP sequence using either CW irradiation or small flip-angle pulses are discussed." @default.
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• W2196604285 date "2016-02-01" @default.
• W2196604285 modified "2023-10-14" @default.
• W2196604285 title "Theoretical description of RESPIRATION-CP" @default.
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• W2196604285 doi "https://doi.org/10.1016/j.cplett.2015.12.043" @default.
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