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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2197771435> ?p ?o ?g. }

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• W2197771435 abstract "Mechanical forces have previously been used to drive reactions along pathways that violate the orbital symmetry effects captured in the Woodward-Hoffmann rules. Here, we show that a polymer lever arm effect can provide a mechanical advantage in accelerating the symmetry forbidden disrotatory ring opening of benzocyclobutene (BCB). Addition of an α-E-alkene to the BCB mechanophore drops the force required to induce reactions on the ∼0.1 s time scale of single-molecule force spectroscopy experiments from 1370 to 920 pN." @default.
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• W2197771435 date "2015-08-19" @default.
• W2197771435 modified "2023-10-18" @default.
• W2197771435 title "Accelerating a Mechanically Driven <i>anti</i>-Woodward–Hoffmann Ring Opening with a Polymer Lever Arm Effect" @default.
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• W2197771435 doi "https://doi.org/10.1021/acs.joc.5b01465" @default.
• W2197771435 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26270991" @default.
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