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- W2199212773 abstract "An efficient Ir(III)-catalyzed C–H activation and annulations of aryloxime with α-diazocarbonyl compounds has been developed for the synthesis of substituted isoquinoline N-oxides. The reaction proceeds under mild atmospheric conditions, without any external oxidants and releases N2 and H2O as the byproducts. In addition, synthetic applications of the N-oxide products have been established by performing further functionalization. An interesting dimeric iridacyclic complex allied through a bis-silver carboxylate bridge has been isolated that efficiently catalyzed the reaction." @default.
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- W2199212773 date "2015-12-29" @default.
- W2199212773 modified "2023-10-18" @default.
- W2199212773 title "Ir(III)-Catalyzed Synthesis of Isoquinoline <i>N</i>-Oxides from Aryloxime and α-Diazocarbonyl Compounds" @default.
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- W2199212773 doi "https://doi.org/10.1021/acs.orglett.5b03462" @default.
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