Matches in SemOpenAlex for { <https://semopenalex.org/work/W2199981402> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W2199981402 abstract "When a reactive intermediate can be isomerized and the isomerized intermediate can further react to give an isomer of an intended product, setting a shorter residence time will suppress such isomerization and allow highly selective synthesis of an intended product. The rate of isomerization is also temperature dependent, and thus, controlling not only the residence time but also the temperature is important. In some cases, the isomerization may proceed completely to give a more stable isomer of the reactive intermediate. In such cases, high-resolution reaction time control allows selective synthesis of either a product derived from the initial intermediate or a product derived from the isomerized intermediate at will. When isomerization of an intermediate gives an equilibrium mixture, setting a shorter residence time will suppress such isomerization and allow highly selective synthesis of a product derived from the intermediate that has yet to be isomerized. This concept basically can be applied to positional isomers and stereoisomers. In particular, this concept is useful in asymmetric synthesis in which epimerization of an optically active intermediate can be suppressed to allow synthesis of a product with high enantiomeric purity." @default.
- W2199981402 created "2016-06-24" @default.
- W2199981402 creator A5046602598 @default.
- W2199981402 date "2015-01-01" @default.
- W2199981402 modified "2023-09-27" @default.
- W2199981402 title "Controlling Isomerization by High-Resolution Reaction Time Control" @default.
- W2199981402 cites W1990542316 @default.
- W2199981402 cites W2029093625 @default.
- W2199981402 cites W2037374748 @default.
- W2199981402 cites W2051444778 @default.
- W2199981402 cites W2078945255 @default.
- W2199981402 cites W2136082411 @default.
- W2199981402 cites W2159811749 @default.
- W2199981402 cites W2322255728 @default.
- W2199981402 cites W4256511543 @default.
- W2199981402 doi "https://doi.org/10.1007/978-4-431-55513-1_6" @default.
- W2199981402 hasPublicationYear "2015" @default.
- W2199981402 type Work @default.
- W2199981402 sameAs 2199981402 @default.
- W2199981402 citedByCount "0" @default.
- W2199981402 crossrefType "book-chapter" @default.
- W2199981402 hasAuthorship W2199981402A5046602598 @default.
- W2199981402 hasConcept C105768512 @default.
- W2199981402 hasConcept C126661725 @default.
- W2199981402 hasConcept C127413603 @default.
- W2199981402 hasConcept C161790260 @default.
- W2199981402 hasConcept C178790620 @default.
- W2199981402 hasConcept C185592680 @default.
- W2199981402 hasConcept C187320778 @default.
- W2199981402 hasConcept C203130289 @default.
- W2199981402 hasConcept C2524010 @default.
- W2199981402 hasConcept C2775913793 @default.
- W2199981402 hasConcept C33923547 @default.
- W2199981402 hasConcept C486523 @default.
- W2199981402 hasConcept C71240020 @default.
- W2199981402 hasConcept C75473681 @default.
- W2199981402 hasConcept C90673727 @default.
- W2199981402 hasConceptScore W2199981402C105768512 @default.
- W2199981402 hasConceptScore W2199981402C126661725 @default.
- W2199981402 hasConceptScore W2199981402C127413603 @default.
- W2199981402 hasConceptScore W2199981402C161790260 @default.
- W2199981402 hasConceptScore W2199981402C178790620 @default.
- W2199981402 hasConceptScore W2199981402C185592680 @default.
- W2199981402 hasConceptScore W2199981402C187320778 @default.
- W2199981402 hasConceptScore W2199981402C203130289 @default.
- W2199981402 hasConceptScore W2199981402C2524010 @default.
- W2199981402 hasConceptScore W2199981402C2775913793 @default.
- W2199981402 hasConceptScore W2199981402C33923547 @default.
- W2199981402 hasConceptScore W2199981402C486523 @default.
- W2199981402 hasConceptScore W2199981402C71240020 @default.
- W2199981402 hasConceptScore W2199981402C75473681 @default.
- W2199981402 hasConceptScore W2199981402C90673727 @default.
- W2199981402 hasLocation W21999814021 @default.
- W2199981402 hasOpenAccess W2199981402 @default.
- W2199981402 hasPrimaryLocation W21999814021 @default.
- W2199981402 hasRelatedWork W108190801 @default.
- W2199981402 hasRelatedWork W1436413986 @default.
- W2199981402 hasRelatedWork W2001765043 @default.
- W2199981402 hasRelatedWork W2006973581 @default.
- W2199981402 hasRelatedWork W2007616254 @default.
- W2199981402 hasRelatedWork W2014192843 @default.
- W2199981402 hasRelatedWork W2027004353 @default.
- W2199981402 hasRelatedWork W2059158090 @default.
- W2199981402 hasRelatedWork W2060429924 @default.
- W2199981402 hasRelatedWork W2068063173 @default.
- W2199981402 hasRelatedWork W2083164790 @default.
- W2199981402 hasRelatedWork W2110414202 @default.
- W2199981402 hasRelatedWork W2115389650 @default.
- W2199981402 hasRelatedWork W2166723485 @default.
- W2199981402 hasRelatedWork W22413302 @default.
- W2199981402 hasRelatedWork W2950831570 @default.
- W2199981402 hasRelatedWork W2951860784 @default.
- W2199981402 hasRelatedWork W3081194165 @default.
- W2199981402 hasRelatedWork W3129544302 @default.
- W2199981402 hasRelatedWork W71598063 @default.
- W2199981402 isParatext "false" @default.
- W2199981402 isRetracted "false" @default.
- W2199981402 magId "2199981402" @default.
- W2199981402 workType "book-chapter" @default.