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- W2200538332 abstract "The investigation or dehydration or hydrated cobalt (II) acetate, as prescribed by various authors, shows that dehydration is accompanied by partial hydrolysis to ror.m at least two dirrerent basic acetates with rough formulas ot co 4 {c2H3 o2 ) 7oH, purple and co5 {c2H3o2 ) 8 (oH) 2 , pink. This thermolysis data is in partial agreement with other recently published results. Evidence is presented which shows that Mallinckrodt's analytical reagent is Co{C2H3o2 ) 2 •2H2o, rather than Co(c2~o2 ) 2 • 4H20. The determination or the structure of cobolt tii) acetate precipitated from glacial acetic acid was approached by inrrared studies, preparation or adducts and magnetic susceptibility measurements. It was found that the cobalt (II) acetate dimer formed in glacial acetic acid is octahedrally coordinated with two coordination sites vacant. It was shown that the binuclear cage structure common to Cu{II), Cr( II) and Rh( II) aceta tea is the probable structure or cobHlt (II) acetate dimer, co2 (c2H302 )4. The primary basis for this conclusion was the infrared studies. Strong evidence is presented indicating that cobalt (II) acetate exists in three distinct structural orientations: Co(c2~o2 ) 2 •4H20, unidentate acetates with bonding mainly ionic in character; Co(C 2H3o2 )2•2820, bidentate acetates with si~e metal atoms and also the possibility of some binuclear bridging acetates; Co2(C2B302) 4 , binuclear cage structure (j with bridging aoetatea. LIST OF FIGURES LIST OF TABLES" @default.
- W2200538332 created "2016-06-24" @default.
- W2200538332 creator A5005771768 @default.
- W2200538332 date "1965-01-01" @default.
- W2200538332 modified "2023-09-27" @default.
- W2200538332 title "Thermal hydrolysis and structure studies on cobalt (II) acetate" @default.
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