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• W2201167545 abstract "Abstract We recently proposed a new battery system based on the redox of lithium peroxide (Li 2 O 2 )/lithium oxide (Li 2 O) at the cathode (lithium-peroxide battery system). In this system, the use of Li 2 O with cobalt ions partially substituted for lithium ions (Co-doped Li 2 O) is key to its realization. In this study, to further improve the cell performance, we prepare various Co-doped Li 2 O samples by a mechanochemical process using different cobalt source materials (e.g., LiCoO 2 , Co 3 O 4 , and CoO) and comparatively investigate them. Amongst the investigated cathode materials, the Co-doped Li 2 O sample prepared using LiCoO 2 with a Co/(Co + Li) ratio of 0.09 exhibits the best performance. Monitoring of the pressure in the cell reveals that this Co-doped Li 2 O cathode can be charged to 270 mAh g −1 without O 2 evolution involving its decomposition. Charge and discharge at 270 mAh g −1 is repeated more than 50 times. In addition, the rate-capability tests reveals that the redox reaction between peroxide and oxide ions is fast and that the cathode can be discharged at a high current density of 1000 mA g −1 ." @default.
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• W2201167545 date "2016-02-01" @default.
• W2201167545 modified "2023-10-03" @default.
• W2201167545 title "Improved performance of Co-doped Li2O cathodes for lithium-peroxide batteries using LiCoO2 as a dopant source" @default.
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• W2201167545 doi "https://doi.org/10.1016/j.jpowsour.2015.12.041" @default.
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