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- W2201207508 abstract "An ethyne-bridged Ni2+ porphyrin-[26]hexaphyrin-Ni2+ porphyrin triad (4) has been prepared and shown to adopt a dumbbell-like conformation despite the two bulky porphyrinylethynyl groups at the hinge positions of the hexaphyrin. The 1H NMR and UV/vis/NIR spectra of 4 revealed that the aromatic nature of the [26]hexaphyrin unit was significantly mitigated via conjugative interaction with the porphyrinylethynyl substituents. Thermal transannular cyclization of 4 proceeded smoothly to give vinylene-bridged triad 12, in which the π-systems of the Ni2+ porphyrins and [26]hexaphyrin are not conjugated and the aromatic character of the latter is enhanced." @default.
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- W2201207508 date "2015-12-29" @default.
- W2201207508 modified "2023-09-28" @default.
- W2201207508 title "An Ethyne-Bridged Porphyrin-Hexaphyrin-Porphyrin Triad That Undergoes a Thermal Transannular Cyclization" @default.
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- W2201207508 doi "https://doi.org/10.1002/ajoc.201500509" @default.
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