Matches in SemOpenAlex for { <https://semopenalex.org/work/W2201257620> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W2201257620 abstract "在单脉冲激波管上,研究了1,2-二氯乙烷的热裂解.实验的激波条件为:温度区间1020 K＜T＜1190 K, 压力: P=0.12 MPa,实验时间τ=0.5 ms;实验气体为1,2-二氯乙烷稀释于Ar气中(3.95 mmol/L).以4-甲基-1-环己烯作为对比速率法实验的内标物,用4-甲基-1-环己烯开环反应的速率常数k=1015.3exp(-33400/T) s-1,以及从其产物的浓度推定出实验温度.经激波加热后的实验气体的终产物用气相色谱分析出主要成分为C2H3Cl,指示出主要反应通道为β消去反应.如把所有产物C2H3Cl都归于β消去反应,则可推定出表观之反应速率常数k1a=5.0×1013exp(-30000/T) s-1.对于由C-Cl键断键反应引发的链反应的可能影响做了分析研究.用了一种简便分析可推知在实验的温度范围内的低端(1020 K)链反应的影响可以忽略,而在其高端(1190 K)链反应将给出10%的终产物C2H3Cl的附加浓度,获得真实的β消去反应速率常数则必须把这部分予以扣除.经过这样的校正之后,最后得到CH2ClCH2Clβ消去反应速率常数为k1c=2.3×1013exp(-29200/T) s-1." @default.
- W2201257620 created "2016-06-24" @default.
- W2201257620 creator A5000422579 @default.
- W2201257620 creator A5018432815 @default.
- W2201257620 creator A5033006193 @default.
- W2201257620 creator A5065912562 @default.
- W2201257620 creator A5082368424 @default.
- W2201257620 date "2002-01-01" @default.
- W2201257620 modified "2023-09-27" @default.
- W2201257620 title "Thermal Decomposition of 1,2-Dichloroethane in a Single-Pulse Shock Tube" @default.
- W2201257620 hasPublicationYear "2002" @default.
- W2201257620 type Work @default.
- W2201257620 sameAs 2201257620 @default.
- W2201257620 citedByCount "0" @default.
- W2201257620 crossrefType "journal-article" @default.
- W2201257620 hasAuthorship W2201257620A5000422579 @default.
- W2201257620 hasAuthorship W2201257620A5018432815 @default.
- W2201257620 hasAuthorship W2201257620A5033006193 @default.
- W2201257620 hasAuthorship W2201257620A5065912562 @default.
- W2201257620 hasAuthorship W2201257620A5082368424 @default.
- W2201257620 hasConcept C120665830 @default.
- W2201257620 hasConcept C121332964 @default.
- W2201257620 hasConcept C124681953 @default.
- W2201257620 hasConcept C126322002 @default.
- W2201257620 hasConcept C160434732 @default.
- W2201257620 hasConcept C161790260 @default.
- W2201257620 hasConcept C178790620 @default.
- W2201257620 hasConcept C185592680 @default.
- W2201257620 hasConcept C192562407 @default.
- W2201257620 hasConcept C2780106024 @default.
- W2201257620 hasConcept C2780167933 @default.
- W2201257620 hasConcept C2781300812 @default.
- W2201257620 hasConcept C33923547 @default.
- W2201257620 hasConcept C57879066 @default.
- W2201257620 hasConcept C71924100 @default.
- W2201257620 hasConcept C94915269 @default.
- W2201257620 hasConcept C97355855 @default.
- W2201257620 hasConceptScore W2201257620C120665830 @default.
- W2201257620 hasConceptScore W2201257620C121332964 @default.
- W2201257620 hasConceptScore W2201257620C124681953 @default.
- W2201257620 hasConceptScore W2201257620C126322002 @default.
- W2201257620 hasConceptScore W2201257620C160434732 @default.
- W2201257620 hasConceptScore W2201257620C161790260 @default.
- W2201257620 hasConceptScore W2201257620C178790620 @default.
- W2201257620 hasConceptScore W2201257620C185592680 @default.
- W2201257620 hasConceptScore W2201257620C192562407 @default.
- W2201257620 hasConceptScore W2201257620C2780106024 @default.
- W2201257620 hasConceptScore W2201257620C2780167933 @default.
- W2201257620 hasConceptScore W2201257620C2781300812 @default.
- W2201257620 hasConceptScore W2201257620C33923547 @default.
- W2201257620 hasConceptScore W2201257620C57879066 @default.
- W2201257620 hasConceptScore W2201257620C71924100 @default.
- W2201257620 hasConceptScore W2201257620C94915269 @default.
- W2201257620 hasConceptScore W2201257620C97355855 @default.
- W2201257620 hasIssue "5" @default.
- W2201257620 hasLocation W22012576201 @default.
- W2201257620 hasOpenAccess W2201257620 @default.
- W2201257620 hasPrimaryLocation W22012576201 @default.
- W2201257620 hasRelatedWork W1969649594 @default.
- W2201257620 hasRelatedWork W1974509178 @default.
- W2201257620 hasRelatedWork W1995523976 @default.
- W2201257620 hasRelatedWork W1998334163 @default.
- W2201257620 hasRelatedWork W2013342362 @default.
- W2201257620 hasRelatedWork W2021250559 @default.
- W2201257620 hasRelatedWork W2023691845 @default.
- W2201257620 hasRelatedWork W2051545206 @default.
- W2201257620 hasRelatedWork W2052424333 @default.
- W2201257620 hasRelatedWork W2095095511 @default.
- W2201257620 hasRelatedWork W2135567550 @default.
- W2201257620 hasRelatedWork W2145289271 @default.
- W2201257620 hasRelatedWork W2315658941 @default.
- W2201257620 hasRelatedWork W2326052725 @default.
- W2201257620 hasRelatedWork W2417554178 @default.
- W2201257620 hasRelatedWork W2469163217 @default.
- W2201257620 hasRelatedWork W2802138867 @default.
- W2201257620 hasRelatedWork W2919231814 @default.
- W2201257620 hasRelatedWork W2952278063 @default.
- W2201257620 hasRelatedWork W2953247153 @default.
- W2201257620 hasVolume "15" @default.
- W2201257620 isParatext "false" @default.
- W2201257620 isRetracted "false" @default.
- W2201257620 magId "2201257620" @default.
- W2201257620 workType "article" @default.