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- W2201617497 abstract "Initial and treated silicas of different origin, such as fumed and precipitated silicas and silica gel, were studied using infrared spectroscopy, DSC, NMR, and adsorption methods. Mechanochemical activation (MCA) of fumed silica A-300 in a ball-mill or a microbreaker affects the structure of aggregates of nanoparticles and agglomerates of aggregates becoming more compacted. Any treatment of ‘soft’ nanosilica affects the interfacial behavior of polar and nonpolar adsorbates because the rearrangement of secondary particles affects the freezing–melting point depression. Clusterization of adsorbates bound in pores causes diminution of heat effects during phase transition (freezing or fusion). The freezing point depression and increasing melting point lead to the hysteresis in freezing–melting of adsorbates bound in pores. The study shows that fumed and precipitated silicas can be more sensitive to external actions, such as wetting–drying and MCA, than silica gels because of less dense packing of nanoparticles in the secondary structures. These effects should be considered upon applications of similar materials in different media." @default.
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- W2201617497 date "2016-03-01" @default.
- W2201617497 modified "2023-10-01" @default.
- W2201617497 title "Influence of structural organization of silicas on interfacial phenomena" @default.
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- W2201617497 doi "https://doi.org/10.1016/j.colsurfa.2015.12.030" @default.
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