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- W2201692911 abstract "Previous studies (Mills & Urey, 1940; Affek, 2013; Clog et. al., 2015) have investigated the rates of oxygen isotopic exchange with CO2 and H2O, as well as the Δ47 for CO2 with liquid water. The understanding of the kinetics of these reactions has led to knowledge of the ease of equilibration of CO2 in the presence of water. We analyze samples at higher temperatures (100°C) than most other laboratories, and are thus interested in the cost of higher water vapor pressures associated with faster reaction times afforded by higher temperatures. Questions remain unanswered surrounding the ease of re-equilibration of CO2 in the presence of liquid water and phosphoric acid in digestion for clumped isotope analyses. We will investigate the kinetics of isotopic exchange between CO2 and H2O as well as CO2 and H3PO4 at 0°C, 25°C and 100°C on varying intervals of time. Exchange between stochastic CO2 and ice (0°C) will be investigated in order to observe the possibility of isotope exchange between a solid and a gas. Such isotope exchange may affect reference frames in different laboratories, contributing to the presence of different sloped calibration lines between laboratories." @default.
- W2201692911 created "2016-06-24" @default.
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- W2201692911 date "2015-01-01" @default.
- W2201692911 modified "2023-09-26" @default.
- W2201692911 title "Isotopic Exchange between CO2-H2O and CO2-H3PO4" @default.
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- W2201692911 hasPublicationYear "2015" @default.
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