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- W220169354 abstract "Subsequent to the work of Olah et al., the direct and competitive kinetics of bromination and chlorination of aromatic compounds, catalysed by AlCl3 has been studied. The rate equation for the bromination of benzene and toluene was determined with great care and the ratio ktol./kbenz., measured by two kinetic methods, is very superior to that given by Olah et al. The chlorination of other aromatic compounds has been discussed along similar lines to benzene and toluene. The observed differences between the two methods have been explained and the selectivity determination by the competitive kinetic method within the limits given has been discussed. These results show that the small selectivities observed by Olah et at. cannot be generalized, as having an effect on the diffusion of the reactants. Therefore, it is not necessary to have a π complex in the rate determining step of the aromatic electrophilic substitution." @default.
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- W220169354 title "Substitution electrophile aromatique" @default.
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